Which element is a strong reducing agent in +2 oxidation state and why?
The element that acts as a strong reducing agent in its +2 oxidation state is Zinc (Zn).
Zinc has a relatively low standard electrode potential:
\( E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, \text{V} \)
This negative value indicates that metallic zinc readily loses electrons to form \( \text{Zn}^{2+} \) ions:
\( \text{Zn} \rightarrow \text{Zn}^{2+} + 2e^- \)
The more negative the \( E^\circ \) value, the stronger the reducing power, as it reflects a higher tendency to donate electrons.
Thus, in the +2 oxidation state, zinc acts as a strong reducing agent and is capable of reducing other chemical species by donating electrons.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Acidified \(KMnO_4\) oxidizes sulphite to:
Complete and balance the following chemical equations: (a) \[ 2MnO_4^-(aq) + 10I^-(aq) + 16H^+(aq) \rightarrow \] (b) \[ Cr_2O_7^{2-}(aq) + 6Fe^{2+}(aq) + 14H^+(aq) \rightarrow \]
Convert Propanoic acid to Ethane