The azeotropic mixture of water and HCl is a mixture in which the two components boil at a constant temperature, and their composition in the vapor phase is the same as in the liquid phase. In the case of water and HCl, this azeotrope forms at a temperature of 381.5 K.
When you distill an azeotropic mixture, it's typically not possible to separate the components into pure states using a simple distillation process. The reason for this is that the composition of the vapor and liquid phases remains constant at the azeotropic point. In the case of water and HCl, as you distill the mixture, the vapor you collect will have the same composition as the liquid you started with, which is the azeotropic composition.
Therefore, You cannot obtain either pure water or pure HCl by distilling the azeotropic mixture because the composition remains constant at 381.5 K.
So, the correct option is (C): Neither water nor HCl.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
A solution is a homogeneous mixture of two or more components in which the particle size is smaller than 1 nm.
For example, salt and sugar is a good illustration of a solution. A solution can be categorized into several components.
The solutions can be classified into three types:
On the basis of the amount of solute dissolved in a solvent, solutions are divided into the following types: