Step 1: Concept
Use the addition formula for inverse tangents: $\tan^{-1} x + \tan^{-1} y = \pi + \tan^{-1}(\frac{x+y}{1-xy})$ if $xy > 1$.
Step 2: Meaning
Calculate $\tan^{-1} 2 + \tan^{-1} 3$ first. Since $2 \times 3 = 6 > 1$, we add $\pi$.
Step 3: Analysis
$\tan^{-1} 2 + \tan^{-1} 3 = \pi + \tan^{-1}(\frac{2+3}{1-6}) = \pi + \tan^{-1}(-1) = \pi - \pi/4 = 3\pi/4$.
Step 4: Conclusion
Adding $\tan^{-1} 1$ (which is $\pi/4$): $\pi/4 + 3\pi/4 = \pi$.
Final Answer: (C)