Question:

Potassium permanganate ($KMnO_{4}$) is called a self-indicator because:

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No extra indicator needed for Permanganate; the purple color does the job.
Updated On: May 25, 2026
  • It forms a precipitate during titration
  • It shows purple colour at the end point
  • It works with starch indicator
  • It is colourless
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The Correct Option is B

Solution and Explanation

Step 1: Concept
In redox titrations, some reagents possess a strong inherent color that changes or persists at the equivalence point.

Step 2: Meaning

A self-indicator eliminates the need for an external chemical indicator like phenolphthalein or methyl orange.

Step 3: Analysis

$KMnO_{4}$ is a deep purple solution. During titration, it is reduced to colorless $Mn^{2+}$. Once the analyte is exhausted, the first excess drop of $KMnO_{4}$ imparts a persistent pink/purple color to the solution.

Step 4: Conclusion

This visible color change at the end point allows $KMnO_{4}$ to function as its own indicator. Final Answer: (B)
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