To solve this question, we need to understand the nature of nucleophilic bimolecular substitution reactions (SN2) involving alkyl halides.
1. Understanding the SN2 Mechanism:
In the SN2 mechanism, the nucleophile attacks the carbon atom bonded to the leaving group from the opposite side of the leaving group. This results in the simultaneous displacement of the leaving group and the formation of a new bond with the nucleophile.
2. Inversion of Configuration:
During the attack by the nucleophile, there is a backside attack on the carbon. This causes the configuration at the chiral center to invert, meaning that if the molecule was initially in the "R" configuration, it will now be in the "S" configuration, and vice versa.
3. Conclusion:
Alkyl halides undergoing nucleophilic bimolecular substitution reactions (SN2) involve an inversion of configuration at the carbon center that is undergoing substitution.
Final Answer:
The correct option is (C) inversion of configuration.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Give the IUPAC names of the following compounds:
(i)CH3CH(Cl)CH(Br)CH3
(ii)CHF2CBrClF
(iii)ClCH2C≡CCH2Br
(iv)(CCl3)3CCl
(v)CH3C(p-ClC6H4)2CH(Br)CH3
(vi)(CH3)3CCH=CClC6H4I-p
Write the structures of the following organic halogen compounds.
(i) 2-Chloro-3-methylpentane
(ii)p-Bromochlorobenzene
(iii)1-Chloro-4-ethylcyclohexane
(iv)2-(2-Chlorophenyl)-1-iodooctane
(v)2-Bromobutane
(vi)4-tert-Butyl-3-iodoheptane
(vii)1-Bromo-4-sec-butyl-2-methylbenzene
(viii)1,4-Dibromobut-2-ene
Which one of the following has the highest dipole moment?
(i)CH2Cl2
(ii)CHCl3
(iii)CCl4
A hydrocarbon C5H10 does not react with chlorine in the dark but gives a single monochloro compound C5H9Cl in bright sunlight. Identify the hydrocarbon.