List of top Chemistry Questions

Among SO₃, NF₃, NH₃, XeF₂, CIF$_3$, and SF₆, the hybridization of the molecule with non-zero dipole moment and one or more lone-pairs of electrons on the central atom is:

A solution is made by mixing one mole of volatile liquid A with 3 moles of volatile liquid B. The vapor pressure of pure A is 200 mm Hg and that of the solution is 500 mm Hg. The vapor pressure of pure B and the least volatile component of the solution, respectively, are:

The property/properties that show irregularity in the first four elements of group-17 are:

An optically active alkyl halide C$_4$H$_9$Br [A] reacts with hot KOH dissolved in ethanol and forms alkene [B] as major product which reacts with bromine to give dibromide [C]. The compound [C] is converted into a gas [D] upon reacting with alcoholic NaNH$_2$. During hydration 18 gram of water is added to 1 mole of gas [D] on warming with mercuric sulphate and dilute acid at 333 K to form compound [E]. The IUPAC name of compound [E] is :

Identify the structure of the final product (D) in the following sequence of the reactions :

Total number of $ sp^2 $ hybridised carbon atoms in product D is _____.

The number of paramagnetic metal complex species among $ [Co(NH_3)_6]^{3+}, [Co(C_2O_4)_3]^{3-}, [MnCl_6]^{3-}, [Mn(CN)_6]^{3-}, [CoF_6]^{3-}, [Fe(CN)_6]^{3-} $ and $ [FeF_6]^{3-} $ with same number of unpaired electrons is _____.

Butane reacts with oxygen to produce carbon dioxide and water following the equation given below:
$ C_4H_{10}(g) + \frac{13}{2} O_2(g) \rightarrow 4CO_2(g) + 5H_2O(l) $ If 174.0 kg of butane is mixed with 320.0 kg of $ O_2 $, the volume of water formed in litres is _____. (Nearest integer)
[Given: (a) Molar masses: C = 12, H = 1, O = 16 g $ mol^{-1} $; (b) Density of water = 1 g $ mL^{-1} $]

In Dumas' method 292 mg of an organic compound released 50 mL of nitrogen gas ($ N_2 $) at 300 K temperature and 715 mm Hg pressure. The percentage composition of 'N' in the organic compound is _____ % (Nearest integer) (Aqueous tension at 300 K = 15 mm Hg)

Only litre buffer solution was prepared by adding 0.10 mol each of $ NH_3 $ and $ NH_4Cl $ in deionised water. The change in pH on addition of 0.05 mol of HCl to the above solution is _____ $ \times 10^{-2} $, (Nearest integer) (Given : $ pK_b $ of $ NH_3 = 4.745 $ and $ \log_{10}3 = 0.477 $)

The extra stability of half-filled subshell is due to
(A) Symmetrical distribution of electrons
(B) Smaller coulombic repulsion energy
(C) The presence of electrons with the same spin in non-degenerate orbitals
(D) Larger exchange energy
(E) Relatively smaller shielding of electrons by one another
Identify the correct statements

Given below are two statements :

In the light of the above statements, choose the most appropriate answer from the options given below :

The number of optically active products obtained from the complete ozonolysis of the given compound is :

The number of unpaired electrons responsible for the paramagnetic nature of the following complex species are respectively : $ [Fe(CN)_6]^{3-}, [FeF_6]^{3-}, [CoF_6]^{3-}, [Mn(CN)_6]^{3-} $

Match List-I with List-II

Choose the correct answer from the options given below :

'X' is the number of acidic oxides among $ VO_2, V_2O_3, CrO_3, V_2O_5 $ and $ Mn_2O_7 $. The primary valency of cobalt in $ [Co(H_2NCH_2CH_2NH_2)_3]_2 (SO_4)_3 $ is Y. The value of X + Y is :

"P" is an optically active compound with molecular formula $ C_6H_{12}O $. When "P" is treated with 2,4-dinitrophenylhydrazine, it gives a positive test. However, in presence of Tollens reagent, "P" gives a negative test. Predict the structure of "P".

Mixture of 1 g each of chlorobenzene, aniline and benzoic acid is dissolved in 50 mL ethyl acetate and placed in a separating funnel, 5 M NaOH (30 mL) was added in the same funnel. The funnel was shaken vigorously and then kept aside. The ethyl acetate layer in the funnel contains :

Given below are two statements :
Statement (I) : On hydrolysis, oligo peptides give rise to fewer number of $ \alpha $-amino acids while proteins give rise to a large number of $ \beta $-amino acids.
Statement (II) : Natural proteins are denatured by acids which convert the water soluble form of fibrous proteins to their water insoluble form.
In the light of the above statements, choose the most appropriate answer from the options given below :

Among, Sc, Mn, Co and Cu, identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is _______BM (in nearest integer).

What is the correct IUPAC name of

Given below are two statements :
Statement I : Hyperconjugation is not a permanent effect.
Statement II : In general, greater the number of alkyl groups attached to a positively charged C-atom, greater is the hyperconjugation interaction and stabilization of the cation.
In the light of the above statements, choose the correct answer from the options given below

Given below are two statements :
Statement I : CrO$ _3 $ is a stronger oxidizing agent than MoO$ _3 $
Statement II : Cr(VI) is more stable than Mo(VI) In the light of the above statements, choose the correct answer from the options given below

In the following series of reactions identify the major products A and B respectively.

The major product (P) in the following reaction is :

Compounds that should not be used as primary standards in titrimetric analysis are : A. Na$ _2 $Cr$ _2 $O$ _7 $ B. Oxalic acid C. NaOH D. FeSO$ _4 $.6H$ _2 $O E. Sodium tetraborate Choose the most appropriate answer from the options given below :