Step 1: Understanding the Concept
In polyfunctional compounds the principal functional group is chosen by a fixed seniority order.
Step 2: Order
Carboxylic acid > sulphonic acid > anhydride > ester > acid halide > amide > nitrile > aldehyde > ketone > alcohol.
Step 3: Compare the options
Among \(-\text{COCl}\), \(-\text{SO}_3\text{H}\), \(-\text{CHO}\) and \(-\text{OH}\), the sulphonic acid group ranks highest.
Final Answer:
The \(-\text{SO}_3\text{H}\) group has the highest priority.
\[ \boxed{\text{(B) }-\mathrm{SO}_{3}\mathrm{H}} \]