What is the effect of temperature on the rate constant of a reaction?
The rate constant of a reaction generally increases with temperature. This is explained by the Arrhenius equation, which shows that the rate constant \(k\) increases exponentially with an increase in temperature. As the temperature rises, the number of molecules having sufficient energy to overcome the activation energy barrier increases, leading to an increase in the rate constant. \[ k = A \cdot e^{-\frac{E_a}{RT}} \] Where: - \(k\) is the rate constant, - \(A\) is the frequency factor, - \(E_a\) is the activation energy, - \(R\) is the gas constant, - \(T\) is the temperature in Kelvin.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.