The conversion of molecule X to Y follows second-order kinetics. If the concentration of X is increased 3 times, how will it affect the rate of formation of Y?
The reaction follows second-order kinetics. The rate law for a second-order reaction is given by: \[ \text{Rate} = k [X]^2 \] Where \( \text{Rate} \) is the rate of the reaction, \( k \) is the rate constant, and \( [X] \) is the concentration of reactant X.
Let the initial concentration of X be \( [X]_0 \). The initial rate of the reaction is: \[ \text{Rate}_0 = k [X]_0^2 \]
When the concentration of X is increased 3 times, the new concentration becomes \( 3[X]_0 \). The new rate is: \[ \text{Rate}_{\text{new}} = k (3[X]_0)^2 = k \times 9 [X]_0^2 \]
The ratio of the new rate to the initial rate is: \[ \frac{\text{Rate}_{\text{new}}}{\text{Rate}_0} = \frac{k \times 9 [X]_0^2}{k [X]_0^2} = 9 \]
When the concentration of X is increased by a factor of 3, the rate of formation of Y will increase by a factor of 9.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.