Step 1: Concept Buna-S is a copolymer formed by the addition polymerization of two different monomers.
Step 2: Meaning The name "Buna-S" comes from Butadiene, Na (Sodium catalyst), and Styrene.
Step 3: Analysis It consists of 1,3-butadiene and styrene in a roughly 3:1 ratio.
Step 4: Conclusion The structure is correctly identified by the option containing the benzene ring (styrene) and the butadiene backbone.
Final Answer: (A)