Step 1: Polystyrene is an addition polymer.
Step 2: The monomer of polystyrene is styrene.
Step 3: Structure of styrene is:
\[
CH_2=CH-C_6H_5
\]
Step 4: During polymerization, the double bond opens and many styrene units join together.
\[
n(CH_2=CH-C_6H_5)\rightarrow [-CH_2-CH(C_6H_5)-]_n
\]
Step 5: Hence, the monomer of polystyrene is:
\[
\boxed{CH_2=CH-C_6H_5}
\]