Step 1: Analyzing the Biological Function of Each Dietary Component:
• (a) Protein: Serves as the primary structural block of cellular tissue, essential for growth and repairing body cells $\rightarrow$ (iii).
• (b) Carbohydrates: Act as the body's primary, readily available metabolic substrate and main source of energy $\rightarrow$ (i).
• (c) Fats: Concentrated energy reserves that dissolve and transport essential fat-soluble vitamins ($A, D, E, K$) $\rightarrow$ (iv).
• (d) Roughage: Non-digestible dietary fiber that adds bulk to feces and assists digestion, contributing negligible caloric energy $\rightarrow$ (ii).
Step 2: Compiling the Ordered Vector:
Matching these pairs gives: (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii). This corresponds exactly to option (D).