Step 1: Understanding the Concept:
Nutrients are divided into macro and micro categories, each serving a primary biological function within the human body.
Step 2: Detailed Explanation:
1. Protein (a): Primarily responsible for growth and the repair of body cells (iii).
2. Carbohydrates (b): The body's main source of energy (i), providing glucose.
3. Fats (c): Essential for transporting fat-soluble vitamins (iv) (A, D, E, K) and long-term energy storage.
4. Roughage (d): Fiber is a non-digestible carbohydrate; it provides negligible energy (ii) but is crucial for digestion.
Step 3: Final Answer: (D) (iii), (i), (iv), (ii).