Question:

Write the reaction involved in Etard reaction.

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Etard reaction converts the side-chain methyl group of aromatic compounds into an aldehyde using chromyl chloride.
Updated On: Jun 29, 2026
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Solution and Explanation

Concept: Etard reaction is a selective oxidation reaction used to convert the methyl group attached to an aromatic ring into an aldehyde group. The reagent used is chromyl chloride \((CrO_2Cl_2)\) in carbon disulphide followed by hydrolysis.

Reaction \[ C_6H_5CH_3 \xrightarrow[\text{CS}_2]{CrO_2Cl_2} \text{Etard Complex} \xrightarrow{H_3O^+} C_6H_5CHO \]

Explanation Toluene undergoes controlled oxidation to benzaldehyde without further oxidation to benzoic acid. This selective oxidation is known as the Etard reaction.

Final Answer \[ \boxed{ C_6H_5CH_3 \xrightarrow[\text{CS}_2]{CrO_2Cl_2} C_6H_5CHO } \]
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