Concept:
Heat treatment affects whey protein denaturation. Higher heat → more denaturation → lower solubility.
Step 1: Understanding HPN index.
• Reflects protein denaturation
• Higher heat → higher denaturation
Step 2: Categories.
• High heat powder → maximum denaturation
• Medium-high heat → next
• Medium heat → moderate
• Low heat → least denaturation
Step 3: Decreasing order.
\[
\text{High} > \text{Medium-high} > \text{Medium} > \text{Low}
\]
Step 4: Mapping.
\[
D, B, C, A
\]
Conclusion: Option (4) correct.