(a) A peptide linkage is a covalent bond that joins two amino acids through the carboxyl group (\(-COOH\)) of one amino acid and the amino group (\(-NH_2\)) of another, forming a \(-CONH-\) bond. This reaction results in the elimination of water (\(H_2O\)) and is known as a peptide bond. \[ \text{Amino acid 1} - \text{COOH} + \text{Amino acid 2} - \text{NH}_2 \rightarrow \text{Peptide bond} + H_2O \]
(b) The DNA double helix is held together primarily by hydrogen bonding between the complementary nitrogenous bases. The adenine (A) base forms two hydrogen bonds with thymine (T), and guanine (G) forms three hydrogen bonds with cytosine (C). These hydrogen bonds are essential for the stability of the double helix structure of DNA.
(c) The correct answer is starch. Starch is a polysaccharide composed of long chains of glucose molecules. It serves as a storage carbohydrate in plants. Sucrose and fructose are monosaccharides or disaccharides, and glucose is a monosaccharide.
(d) - Water-soluble vitamins: Vitamin B and Vitamin C. - Fat-soluble vitamins: Vitamin A, D, E, K. These vitamins are classified based on their solubility, with water-soluble vitamins dissolving in water and fat-soluble vitamins dissolving in fats and oils.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.