The atomization enthalpy of \(CH_4\) is \(1660\ \text{kJ mol}^{-1}\). The C-H bond enthalpy of each successive step in
\[
CH_4 \rightarrow CH_3 \rightarrow CH_2 \rightarrow CH \rightarrow C
\]
are \(+15\), \(+30\) and \(+45\ \text{kJ mol}^{-1}\) higher than the mean bond enthalpy of C-H bonds, respectively. The bond enthalpy of the last C-H unit is