Question:

Which type of isomerism is exhibited by the following complex? \[ [Pt(NH_3)_2Cl_2] \]

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Square planar complexes often show cis–trans isomerism. Classic example: \([Pt(NH_3)_2Cl_2]\) (cisplatin).
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Solution and Explanation

Concept: The complex \([Pt(NH_3)_2Cl_2]\) is a square planar complex of Pt(II). Square planar complexes can show
geometrical isomerism.
Step 1: Possible arrangements. Two possible arrangements:

  • Cis form – Similar ligands adjacent to each other.

  • Trans form – Similar ligands opposite to each other.

Step 2: Types of isomers.
  • Cis-\([Pt(NH_3)_2Cl_2]\)
  • Trans-\([Pt(NH_3)_2Cl_2]\)

Conclusion: \[ \therefore \text{The complex exhibits geometrical (cis–trans) isomerism. \]
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