Question:

Which test is used to distinguish between primary, secondary and tertiary amine?

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Think of the classic benzenesulfonyl chloride plus KOH test for amines.
Updated On: Jul 3, 2026
  • Lucas test
  • Hinsberg test
  • Baeyer test
  • Molisch test
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The Correct Option is B

Solution and Explanation

Step 1: The Hinsberg test uses benzenesulfonyl chloride with aqueous KOH.
Step 2: A primary amine forms a sulfonamide with an acidic N-H, dissolving as its potassium salt in KOH.
Step 3: A secondary amine forms a sulfonamide with no acidic N-H, insoluble in KOH.
Step 4: A tertiary amine does not react at all, remaining as an oily layer.
\[\boxed{\text{Hinsberg test}}\]
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