Which reagents are required for one step conversion of Chlorobenzene to Diphenyl?
Show Hint
- Chlorobenzene, Na, Dry ether
- Benzene, Anhydrous AlCl3
- Chlorobenzene/Fe, Dark
- NaNO2 + HCl
The Correct Option is A
Solution and Explanation
Top CBSE CLASS XII Chemistry Questions
- ${AgNO_3}$ does not decompose where :
- Azeotropic mixture of water and HCl boils at 381.5 K. By distilling the mixture it is possible to obtain
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylanilineAccount for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Top CBSE CLASS XII Organic Reactions Questions
- (A) An organic compound \( A \), molecular formula \( C_2H_6O \), oxidises with \( Cr_2O_7 \) to form a compound \( B \). Compound \( B \) on warming with iodine and aqueous solution of NaOH gives a yellow precipitate of compound \( C \). When compound \( A \) is heated with conc. \( H_2SO_4 \) at 413 K, it gives a compound \( D \), which on reaction with excess HI gives compound \( E \). Identify compounds \( A \), \( B \), \( C \), \( D \), and \( E \) and write chemical equations involved.
- (B) (a) Write chemical equations of the following reactions: (i) Phenol is treated with conc. \( HNO_3 \).
(ii) Propene is treated with \( B_2H_6 \) followed by oxidation by \( H_2O_2 / OH^- \).
(iii) Sodium t-butoxide is treated with \( CH_3Cl \). - (c) How will you convert the following:
(i) Toluene to benzoic acid.
(ii) Ethanol to propan-2-ol.
(iii) Propanal to 2-hydroxy propanoic acid. - (B) Complete each synthesis by giving missing starting material, reagent, or products:
\includegraphics[width=0.5\linewidth]{ch32i.png} - What will be formed after oxidation of secondary alcohol with chromic anhydride (CrO3)?
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