Which one of the following is a disaccharide? \[ \text{Glucose, Lactose, Amylose, Fructose} \]
A disaccharide is a carbohydrate composed of two monosaccharide units joined by a glycosidic bond. Let's explore the components involved in this category.
- Glucose and fructose are monosaccharides, meaning they are single sugar units. - Lactose is a disaccharide composed of two monosaccharides: glucose and galactose. - Amylose is a polysaccharide made up of multiple glucose units.
Thus, out of the given options, lactose is the disaccharide, formed by the glycosidic bond between glucose and galactose.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.