Step 1: Understanding isoelectronic and isostructural concepts.
- Isoelectronic species have the same total number of electrons.
- Isostructural species have the same shape and hybridization.
Step 2: Analyzing the given pairs.
- \( IBr_2^- \) and \( XeF_2 \) both have 22 valence electrons.
- Both species have a linear structure due to sp\(^3\)d hybridization with three lone pairs.