Step 1: Catenation depends on X-X bond energy. S-S~226, higher than P-P~200, Se-Se~172.
Step 2: Cl-Cl high energy but Cl doesn't catenate (octet complete with 1 bond).
Step 3: S forms S8 rings and long plastic sulfur chains, most extensive catenation.
\[\boxed{\text{S shows the highest catenation ability}}\]