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among the following pentachlorides which one does
Question:
Among the following pentachlorides, which one does not exist due to the inert pair effect?
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Think about which group 15 element shows the strongest inert pair effect.
CPET - 2025
CPET
Updated On:
Jul 3, 2026
PCl5
BiCl5
SbCl5
AsCl5
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Verified By Collegedunia
The Correct Option is
B
Solution and Explanation
Step 1:
Inert pair effect strongest for heaviest group 15 element, Bi.
Step 2:
Bi prefers +3 over +5, so BiCl5 too unstable.
Step 3:
PCl5, AsCl5, SbCl5 are all stable known compounds.
\[\boxed{\text{BiCl}_5 \text{ does not exist}}\]
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