Step 1: Recall what Calgon is.
Calgon is sodium hexametaphosphate, which is commonly used for softening hard water.
Its molecular formula is:
\[
(NaPO_3)_6
\]
Step 2: Determine the empirical formula.
The empirical formula is the simplest whole number ratio of atoms present in the compound.
From the molecular formula:
\[
(NaPO_3)_6
\]
The simplest repeating unit is:
\[
NaPO_3
\]
Thus, the empirical formula is:
\[
NaPO_3
\]
Step 3: Match with the given options.
The correct option is:
\[
(3)\;NaPO_3
\]
Step 4: Final conclusion.
Hence, the empirical formula of Calgon is:
\[
\boxed{NaPO_3}
\]