Concept:
Water softening is the process of removing calcium, magnesium, and certain other metal cations in hard water. Various chemical and physical methods are used:
• Calgon method: Uses sodium hexametaphosphate to form complex soluble salts with calcium and magnesium ions.
• Ion exchange method (Permutit): Uses zeolites (hydrated sodium aluminum silicate) to exchange sodium ions with hardness-causing ions.
• Clark's method: A chemical method involving the addition of a calculated amount of lime to remove temporary hardness.
• Synthetic resin method: Uses organic polymers with acidic or basic groups (like sulfonic acid groups) for cation/anion exchange.
Step 1: Matching Calgon method.
Calgon is a trade name forSodium hexametaphosphate, represented by the formulaNa\(_6\)(PO\(_3\))\(_6\).
Therefore,A matches with IV.
Step 2: Matching Ion exchange and Clark's method.
The Ion exchange method (Zeolite process) usesSodium aluminum silicate, formulaNaAlSiO\(_4\).
Therefore,B matches with III.
Clark's method specifically involves the addition ofSlaked lime, formulaCa(OH)\(_2\), to precipitate carbonates.
Therefore,C matches with II.
Step 3: Matching Synthetic resin method.
Synthetic resins used for cation exchange are large organic molecules containing groups like-SO\(_3\)H (sulfonic acid groups), represented asRSO\(_3\)H.
Therefore,D matches with I.