Question:

Match the water softening methods in List-1 with the chemicals/reagents in List-2: [h] {|l|l|} List -1 (Method) & List -2 (Reagent)
(A) Calgon method & (I) RSO\(_3\)H
(B) Ion exchange method & (II) Ca(OH)\(_2\)
(C) Clark's method & (III) NaAlSiO\(_4\)
(D) Synthetic resin method & (IV) Na\(_6\)(PO\(_3\))\(_6\)

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Remember:Calgon =Complex (Sodium hexametaphosphate),Clark's =Calcium hydroxide (Lime). This "C" mnemonic helps distinguish the two chemical methods.
Updated On: Jun 3, 2026
  • A-III, B-IV, C-II, D-I
  • A-IV, B-III, C-II, D-I
  • A-IV, B-I, C-II, D-III
  • A-III, B-I, C-IV, D-II
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The Correct Option is B

Solution and Explanation

Concept: Water softening is the process of removing calcium, magnesium, and certain other metal cations in hard water. Various chemical and physical methods are used:
Calgon method: Uses sodium hexametaphosphate to form complex soluble salts with calcium and magnesium ions.
Ion exchange method (Permutit): Uses zeolites (hydrated sodium aluminum silicate) to exchange sodium ions with hardness-causing ions.
Clark's method: A chemical method involving the addition of a calculated amount of lime to remove temporary hardness.
Synthetic resin method: Uses organic polymers with acidic or basic groups (like sulfonic acid groups) for cation/anion exchange.

Step 1:
Matching Calgon method.
Calgon is a trade name forSodium hexametaphosphate, represented by the formulaNa\(_6\)(PO\(_3\))\(_6\). Therefore,A matches with IV.

Step 2:
Matching Ion exchange and Clark's method.
The Ion exchange method (Zeolite process) usesSodium aluminum silicate, formulaNaAlSiO\(_4\). Therefore,B matches with III. Clark's method specifically involves the addition ofSlaked lime, formulaCa(OH)\(_2\), to precipitate carbonates. Therefore,C matches with II.

Step 3:
Matching Synthetic resin method.
Synthetic resins used for cation exchange are large organic molecules containing groups like-SO\(_3\)H (sulfonic acid groups), represented asRSO\(_3\)H. Therefore,D matches with I.
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