To solve the problem, we need to determine the correct IUPAC name of the complex [Pt(NH3)2Cl2]$^{2+}$.
1. Identifying the Central Metal Ion:
The central metal ion in the complex is platinum (Pt), which has a charge of +2, as indicated by the overall charge of the complex being +2.
2. Identifying the Ligands:
The ligands present in the complex are ammonia (NH3) and chloride (Cl-). Ammonia is a neutral ligand, and chloride is a monodentate anionic ligand.
3. Naming the Ligands:
The ligand ammonia is named "ammine," and chloride is named "chloro." There are two of each ligand in the complex.
4. Determining the Oxidation State of Platinum:
To determine the oxidation state of platinum, we assign oxidation states to the ligands. Ammonia is neutral, and chloride has a charge of -1. Let the oxidation state of platinum be x. The total charge of the complex is +2, so we have the equation:
x + 2(-1) = +2
Solving for x: x - 2 = +2, so x = +4.
5. Writing the Full Name:
According to the IUPAC nomenclature, the complex is named by first naming the ligands in alphabetical order, followed by the central metal ion with its oxidation state in parentheses.
Final Answer:
The correct IUPAC name of [Pt(NH3)2Cl2]$^{2+}$ is "diamminedichloroplatinum(IV) ion."
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
\(FeSO_4\) solution mixed with\( (NH_4)_2SO_4 \) solution in\( 1:1\) molar ratio gives the test of \(Fe^{2+}\) ion but \(CuSO_4\) solution mixed with aqueous ammonia in \( 1:4 \) molar ratio does not give the test of \(Cu^{2+}\) ion. Explain why?
Specify the oxidation numbers of the metals in the following coordination entities:
(i)\( [Co(H_2O)(CN)(en)_2] ^{2+}\)
(ii) \([CoBr_2(en)_2]^{+}\)
(iii)\( [PtCl_4]^{ 2–} \)
(iv) \(K_3[Fe(CN)_6]\)
(v) \([Cr(NH_3)_3Cl_3] \)