Question:

The correct formula of Hinsberg’s reagent is :

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Hinsberg's reagent = Benzenesulphonyl chloride \[ C_6H_5SO_2Cl \] Used in the Hinsberg test to distinguish primary, secondary and tertiary amines.
Updated On: Jun 29, 2026
  • \(C_6H_5COCl\)
  • \(C_6H_5SO_2Cl\)
  • \(C_6H_5CONHCH_3\)
  • \(C_6H_5CH_2NH_2\)
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The Correct Option is B

Solution and Explanation

Concept: Hinsberg's reagent is benzenesulphonyl chloride. It is widely used in the Hinsberg test for distinguishing primary, secondary and tertiary amines. Its molecular formula is \[ C_6H_5SO_2Cl \] The reagent reacts differently with different classes of amines, making it useful for identification purposes.

Step 1: Recalling the reagent used in the Hinsberg test. The Hinsberg test employs benzenesulphonyl chloride. Its structure contains \[ C_6H_5-SO_2-Cl \] Therefore, its molecular formula is \[ C_6H_5SO_2Cl \]

Step 2: Comparing with the given options. Option (A) represents benzoyl chloride. Option (B) represents benzenesulphonyl chloride. Option (C) is an amide derivative. Option (D) is benzylamine. Thus only Option (B) corresponds to Hinsberg's reagent.

Step 3: Selecting the correct answer. Hence the correct formula of Hinsberg's reagent is \[ C_6H_5SO_2Cl \] Therefore, \[ \boxed{\text{Option (B)}} \]
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