Step 1: Concept
Carbon fixation in the Calvin cycle (C$_3$ pathway).
Step 2: Meaning
The enzyme RuBisCO (ribulose-1,5-bisphosphate carboxylase/oxygenase) catalyses the first step of carbon fixation.
Step 3: Analysis
Rubisco (A): Catalyses addition of CO$_2$ to RuBP, forming two molecules of 3-phosphoglycerate --- correct.
PEP Carboxylase (B): Fixes CO$_2$ in C$_4$ plants (mesophyll cells), not in the Calvin cycle.
NADP reductase (C): Involved in light reactions, not carbon fixation.
ATP synthase (D): Produces ATP in light reactions, not carbon fixation.
Step 4: Conclusion
RuBisCO catalyses CO$_2$ fixation onto RuBP in the Calvin cycle.
Final Answer: (A)