Step 1: Silver articles slowly become black when exposed to air for a long time.
Step 2: This black coating is called tarnish.
Step 3: Air contains small amounts of sulphur compounds such as hydrogen sulphide.
Step 4: Silver reacts with sulphur compounds to form silver sulphide.
\[
2Ag+H_2S \rightarrow Ag_2S+H_2
\]
Step 5: The black layer formed is mainly silver sulphide.
\[
\boxed{\text{Its sulphide layer}}
\]