Step 1: Understanding the genetic cross.
In this question, we are dealing with a cross between two plants with genotypes "VV" (homozygous violet) and "vv" (homozygous white).
Step 2: Punnett square analysis.
The cross between "VV" and "vv" will produce all heterozygous "Vv" offspring, since each parent contributes one allele. The "V" allele (violet) is dominant, so all offspring will have violet flowers.
Step 3: Conclusion.
Thus, 100% of the offspring from the cross "VV × vv" will have violet flowers.
Final Answer: 100%.