Question:

In aqueous acidified solution, CrO$_4^{2-}$ ion converts to which of the following ?

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Chromate ion (yellow) converts into dichromate ion (orange) in acidic medium, while dichromate converts back into chromate in alkaline medium.
Updated On: Jun 29, 2026
  • CrO$_3$
  • Cr$^{3+}$
  • Cr$_2$O$_7^{2-}$
  • CrO
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The Correct Option is C

Solution and Explanation

Concept: Chromate and dichromate ions exist in equilibrium in aqueous solution. The equilibrium depends strongly on the pH of the medium. \[ 2CrO_4^{2-}+2H^+ \rightleftharpoons Cr_2O_7^{2-}+H_2O \] Addition of acid increases the concentration of \(H^+\) ions and shifts the equilibrium towards dichromate ion.

Step 1: Nature of chromate ion. Chromate ion is: \[ CrO_4^{2-} \] It is yellow in colour.

Step 2: Effect of acidification. When acid is added: \[ [H^+] \] increases. According to Le Chatelier's principle, the equilibrium shifts in the forward direction. \[ 2CrO_4^{2-}+2H^+ \rightarrow Cr_2O_7^{2-}+H_2O \]

Step 3: Product formed. The product formed is dichromate ion: \[ Cr_2O_7^{2-} \] which is orange in colour.

Step 4: Final answer. \[ \boxed{Cr_2O_7^{2-}} \] Hence option (C) is correct.
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