Concept:
The vector product (or cross product) of two non-zero vectors \( \vec{a} \) and \( \vec{b} \) is equal to the zero vector \( \vec{0} \) if and only if the two vectors are collinear or parallel to each other.
If \( \vec{a} = a_1\hat{i} + a_2\hat{j} + a_3\hat{k} \) and \( \vec{b} = b_1\hat{i} + b_2\hat{j} + b_3\hat{k} \), then their cross product can be computed using the determinant method:
\[
\vec{a} \times \vec{b} = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ a_1 & a_2 & a_3 \\ b_1 & b_2 & b_3 \end{vmatrix} = \vec{0}
\]
Alternatively, since parallel vectors have proportional components, we can apply the condition:
\[
\frac{a_1}{b_1} = \frac{a_2}{b_2} = \frac{a_3}{b_3}
\]
Step 1: Identifying the vector components.
Let us define the two given vectors explicitly:
\[
\vec{a} = 3\hat{i} - 2\hat{j} + 5\hat{k}
\]
\[
\vec{b} = 4\hat{i} + p\hat{j} + q\hat{k}
\]
Here, the corresponding coefficients are:
a_1 &= 3, a_2 = -2, a_3 = 5
b_1 &= 4, b_2 = p, b_3 = q
Step 2: Setting up the collinearity condition.
Since \( \vec{a} \times \vec{b} = \vec{0} \), the components of the vectors must be directly proportional:
\[
\frac{3}{4} = \frac{-2}{p} = \frac{5}{q}
\]
Step 3: Solving for \(p\).
By equating the first two ratios:
\[
\frac{3}{4} = \frac{-2}{p}
\]
Cross-multiplying to solve for \(p\):
\[
3 \times p = -2 \times 4 \implies 3p = -8 \implies p = -\frac{8}{3}
\]
Step 4: Solving for \(q\).
By equating the first and third ratios:
\[
\frac{3}{4} = \frac{5}{q}
\]
Cross-multiplying to solve for \(q\):
\[
3 \times q = 5 \times 4 \implies 3q = 20 \implies q = \frac{20}{3}
\]
Thus, the values are \(p = -\frac{8}{3}\) and \(q = \frac{20}{3}\), which matches option (B).