Step 1: Concept According to Avogadro's Law, equal moles of any gas contain the same number of molecules at S.T.P.
Step 2: Meaning Calculate moles (Mass Molecular Weight) for Option (C):
Moles of $H_{2}$ = $5 / 2 = 2.5$ moles.
Moles of $CH_{4}$ = $40 / 16 = 2.5$ moles.
Step 3: Analysis Since both gases in Option (C) have exactly 2.5 moles, they contain an equal number of molecules.
Step 4: Conclusion Option (C) is the correct pair.
Final Answer: (C)