Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names. (ii)Classify the isomers of alcohols in question 11.3(i)as primary, secondary and tertiary alcohols.
Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names. (ii)Classify the isomers of alcohols in question 11.3(i)as primary, secondary and tertiary alcohols.
Solution and Explanation
(i)The structures of all isomeric alcohols of molecular formula,C5H12O are shown below:
(ii)Primary alcohol:Pentan-1-ol;2-Methylbutan-1-ol;
3-Methylbutan-1-ol;2,2-Dimethylpropan-1-ol
Secondary alcohol:Pentan-2-ol;3-Methylbutan-2-ol;
Pentan-3-ol
Tertiary alcohol:2-methylbutan-2-ol
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Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylanilineAccount for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
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Write the IUPAC names of the following compounds:
Write structures of the compounds whose IUPAC names are as follows:
(i)2-Methylbutan-2-ol
(ii)1-Phenylpropan-2-ol
(iii)3,5-Dimethylhexane -1,3,5-triol
(iv)2,3-Diethylphenol
(v)1- Ethoxypropane
(vi)2-Ethoxy-3-methylpentane
(vii)Cyclohexylmethanol
(viii)3-Cyclohexylpentan-3-ol
(ix)Cyclopent-3-en-1-ol
(x)3-Chloromethylpentan-1-ol.
Explain why propanol has a higher boiling point than that of the hydrocarbon, butane.
Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.
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