\((CH_3)_3C-OC_2H_5\) on reaction with HI gives
Show Hint
- \((CH_3)_3C-I\) and \(C_2H_5-I\)
- \((CH_3)_3C-OH\) and \(C_2H_5-I\)
- \((CH_3)_3C-I\) and \(C_2H_5-OH\)
- \((CH_3)_3C-OH\) and \(C_2H_5-OH\)
The Correct Option is C
Solution and Explanation
When an ether is cleaved by HI, the bond breaks so that the iodide attaches to the alkyl group that can form the more stable carbocation. For ethers with a tertiary group, the reaction follows an \(SN1\) path through the stable tertiary carbocation.
Step 1:
In \((CH_3)_3C-OC_2H_5\), the tert-butyl group forms a very stable tertiary carbocation \((CH_3)_3C^+\), so it takes the iodide to give \((CH_3)_3C-I\).
Step 2:
The remaining ethyl part leaves as \(C_2H_5OH\) (the oxygen stays with the ethyl group). So products are \((CH_3)_3C-I\) and \(C_2H_5-OH\).
Answer: Option (C) \((CH_3)_3C-I\) and \(C_2H_5-OH\).
Top CBSE CLASS XII Chemistry Questions
- ${AgNO_3}$ does not decompose where :
- Azeotropic mixture of water and HCl boils at 381.5 K. By distilling the mixture it is possible to obtain
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylanilineAccount for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Top CBSE CLASS XII Chemical Reactions of Alcohols Phenols and Ethers Questions
Calculate the potential for half-cell containing 0.01 M K\(_2\)Cr\(_2\)O\(_7\)(aq), 0.01 M Cr\(^{3+}\)(aq), and 1.0 x 10\(^{-4}\) M H\(^+\)(aq).
- Write the reaction involved in Kolbe's reaction.
- An organic compound ‘A’, with molecular formula $C_2H_6O$ reacts with active metals such as sodium to give compound ‘B’ and hydrogen gas. ‘A’ on treatment with iodine and sodium hydroxide gives ‘C’ and in presence of $H_2SO_4$ at $413$ K gives ‘D’ ($C_4H_{10}O$). ‘D’ on reaction with excess of HI gives ‘E’. Identify ‘A’, ‘B’, ‘C’, ‘D’ and ‘E’ and write all the reactions involved.
- Lucas reagent produces cloudiness immediately with :
- Write the mechanism of acid dehydration of ethanol to yield ethene.
Top CBSE CLASS XII Questions
- 2, b, c are in A.P. and the range of determinant $\begin{vmatrix}1&1&1\\ 2&b&c\\ 4&b^{2}&c^{2}\end{vmatrix}$ is [2, 16]. Then find range of c is
- A boy of mass 50 kg is standing at one end of a, boat of length 9 m and mass 400 kg. He runs to the other, end. The distance through which the centre of mass of the boat boy system moves is
- A capillary tube of radius r is dipped inside a large vessel of water. The mass of water raised above water level is M. If the radius of capillary is doubled, the mass of water inside capillary will be
- A circular disc is rotating about its own axis. An external opposing torque 0.02 Nm is applied on the disc by which it comes rest in 5 seconds. The initial angular momentum of disc is
- A circular disc is rotating about its own axis at uniform angular velocity \(\omega.\) The disc is subjected to uniform angular retardation by which its angular velocity is decreased to \(\frac {\omega}{2}\) during 120 rotations. The number of rotations further made by it before coming to rest is