Step 1: Ecological classification of plants by substratum (edaphic factors) includes groups like oxylophytes (plants of acidic, humus rich soils), psammophytes (plants growing on sandy substratum) and chasmophytes (plants growing in rock crevices).
Step 2: Sciophytes are shade-loving plants, this grouping is based on light availability, not on the type of substratum.
Step 3: Since the question asks for substratum-based groups, the one that does not belong here is sciophytes.