Question:

According to Werner’s theory, the primary valencies of the central metal atom :

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Primary valency = Oxidation state = Ionisable. Secondary valency = Coordination number = Non-ionisable.
Updated On: Jun 29, 2026
  • are satisfied by neutral molecules or negative ions.
  • are equal to its coordination number.
  • are satisfied by negative ions.
  • are non-ionisable.
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The Correct Option is C

Solution and Explanation

Concept: Werner proposed two types of valencies:

• Primary valency

• Secondary valency

Step 1: Primary valency. Primary valency corresponds to oxidation state. These are ionisable. These are satisfied by negative ions.

Step 2: Secondary valency. Secondary valency corresponds to coordination number. These are non-ionisable. These are satisfied by ligands.

Step 3: Evaluate options. (A) Describes secondary valency. (B) Incorrect. (C) Correct. (D) Incorrect because primary valencies are ionisable. \[ \boxed{(C)} \]
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