Define the following:
(i) Cell potential
(ii) Fuel Cell
(i) Cell potential, also known as the electrode potential or electromotive force (EMF), is the difference in electric potential between two electrodes in a galvanic or electrochemical cell. It is a measure of the ability of a cell to drive an electrochemical reaction and is usually measured in volts (V). The greater the cell potential, the greater the ability of the cell to perform work. The standard cell potential is calculated under standard conditions, typically 25°C, 1 M concentration for solutions, and 1 atm pressure for gases.
(ii) Fuel cell
A fuel cell is an electrochemical device that converts the chemical energy of a fuel (usually hydrogen) and an oxidant (such as oxygen) into electrical energy. This conversion occurs through a redox reaction at the electrodes. The fuel cell operates continuously as long as the fuel and oxidant are supplied, making it a clean and efficient source of power. Common examples include hydrogen fuel cells used in electric vehicles and other energy applications.
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i) (CH3 )2CHNH2 (ii) CH3 (CH2 )2NH2 (iii) CH3NHCH(CH3 )2
(iv) (CH3 )3CNH2 (v) C6H5NHCH3 (vi) (CH3CH2 )2NCH3 (vii) m–BrC6H4NH2
Give one chemical test to distinguish between the following pairs of compounds.
(i) Methylamine and dimethylamine
(ii) Secondary and tertiary amines
(iii) Ethylamine and aniline
(iv) Aniline and benzylamine
(v) Aniline and N-methylaniline
Account for the following:
(i) pKb of aniline is more than that of methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not.
(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
(v) Aniline does not undergo Friedel-Crafts reaction.
(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.