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Chemistry
List of top Chemistry Questions asked in JEE Main
\({(1) \,N_2(g) +3H_2(g)<=> 2NH_3(g), K_1}\)
\({(2) \,N_2(g) +O_2(g)<=> 2NHO(g), K_2}\)
\({(3) \,H_2(g) +\frac{1}{2}O_2(g)<=> H_2O(g), K_3}\)
The equation for the equilibrium constant of the reaction
\({2NH_3(g) +\frac{5}{2}O_2(g)<=> 2NO(g), 3H_2O(g)}\)
,
\((K_4)\)
in terms of
\(K_1\)
and
\(K_3\)
is:
JEE Main - 2013
JEE Main
Chemistry
Equilibrium
The first ionisation potential of
$Na$
is
$5.1\, eV$
. The value of electron gain enthalpy of
$Na^+$
will be
JEE Main - 2013
JEE Main
Chemistry
Classification
In which of the following pairs of molecules/ions both the species are not likely to exist?
JEE Main - 2013
JEE Main
Chemistry
Chemical bonding and molecular structure
Which of the following represents the correct order of increasing first ionisation enthalpy for
$Ca, Ba, S, Se$
and
$Ar$
?
JEE Main - 2013
JEE Main
Chemistry
Classification of elements and periodicity in properties
For gaseous state, if most probable speed is denoted by
$c *$
, average speed by
$\overline{C}$
and root square speed by
$c$
, then for a large number of molecules, the ratios of these speeds are
JEE Main - 2013
JEE Main
Chemistry
States of matter
Given,
$E^\circ _{Cr ^{3+}/Cr} =-0.74\, V;E^\circ_{MnO^-_4/Mn^{2+}}=1.51\, V$
$\, \, \, \, \, E^\circ _{Cr_2 O ^{2-}_7/Cr^{3+}} =-1.33\, V;E^\circ_{Cl/Cl^-}=1.36\, V$
Based on the data given above strongest oxidising agent will be
JEE Main - 2013
JEE Main
Chemistry
Redox reactions
Which one of the following molecules is expected to exhibit diamagnetic behaviour?
JEE Main - 2013
JEE Main
Chemistry
Chemical bonding and molecular structure
The rate of a reaction doubles when its temperature changes from
$300\, K$
to
$310\,K$
. Activation energy of such a reaction will be
$(R = 8.314 JK^{-1} \,mol^{-1}$
and
$log \,2 = 0.301)$
JEE Main - 2013
JEE Main
Chemistry
Chemical Kinetics
Four successive members of the first row transition elements listed below with atomic numbers. Which one of them is expected to have the highest
$E_{m{^{3+}}/m{^{2+}}}^{\circ}$
value?
JEE Main - 2013
JEE Main
Chemistry
d block elements
Consider the following reaction,
$xMnO_4^- + yC_2O_4^{2-}+zH^+ \rightarrow xMn^{2+}+2yCO_2 + \frac{z}{2}H_2O$
The values of x, y and z in the reaction are, respectively
JEE Main - 2013
JEE Main
Chemistry
d block elements
Which of the following arrangements does not represent the correct order of the property stated against it?
JEE Main - 2013
JEE Main
Chemistry
d block elements
\(12\, g\)
of a nonvolatile solute dissolved in
\(108\, g\)
of water produces the relative lowering of vapor pressure of
\(0.1.\)
The molecular mass of the solute is :
JEE Main - 2013
JEE Main
Chemistry
Solutions
A compound with molecular mass
$180$
is acylated with
$CH_3COCl$
to get a compound with molecular mass
$390$
. The number of amino groups present per molecule of the former compound is
JEE Main - 2013
JEE Main
Chemistry
Amines
A major component of Borsch reagent is obtained by reacting hydrazine hydrate with which of the following ?
JEE Main - 2013
JEE Main
Chemistry
Haloalkanes and Haloarenes
A solution of
$(-) 1-chloro-1-$
phenylethane in toluene racemises slowly in the presence of a small amount of
$SbCl_5$
, due to the formation of
JEE Main - 2013
JEE Main
Chemistry
Haloalkanes and Haloarenes
The order of increasing sizes of atomic radii among the elements
$O, S, Se$
and
$As$
is :
JEE Main - 2013
JEE Main
Chemistry
Classification
An ether (A),
$C_5H_{12}O$
, when heated with excess of hot concentrated
$HI$
produced two alkyl halides which when treated with
$NaOH$
yielded compounds (B) and (C). Oxidation of (B) and (C) gave a propanone and an ethanoic acid respectively. The IUPAC name of the ether (A) is :
JEE Main - 2013
JEE Main
Chemistry
Phenols
Arrange the following compounds in the order of decreasing acidity
JEE Main - 2013
JEE Main
Chemistry
Phenols
Arrange in the correct order of stability (decreasing order) for the following molecules :
JEE Main - 2013
JEE Main
Chemistry
Organic Chemistry
Compound
$( A ), C_8H_9Br$
gives a white precipitate when warmed with alcoholic
$AgNO_3$
. Oxidation of
$(A)$
gives an acid
$(B)$
,
$C_8H_6O$
4.
$(B)$
easily forms anhydride on heating. Identify the compound
$(A)$
.
JEE Main - 2013
JEE Main
Chemistry
Aldehydes, Ketones and Carboxylic Acids
Calcination is the process in which:
JEE Main - 2013
JEE Main
Chemistry
General Principles and Processes of Isolation of Elements
Bond distance in
$HF$
is
$9.17 \times 10^{-11}\, m$
. Dipole moment of
$HF$
is
$6.10^4 \times 10^{-30}\, Cm$
. The percentage ionic character in
$HF$
will be : (electron charge
$= 1.60 \times 10^{-19}\, C$
)
JEE Main - 2013
JEE Main
Chemistry
Chemical bonding and molecular structure
Electron gain enthalpy with negative sign of fluorine is less than that of chlorine due to :
JEE Main - 2013
JEE Main
Chemistry
p -Block Elements
Equimolar solutions of the following compounds are prepared separately in water. Which will have the lowest pH value ?
JEE Main - 2013
JEE Main
Chemistry
Equilibrium
Experimentally it was found that a metal oxide has formula
$ M_{0.98}O. $
Metal
$M$
, present as
$ M^{2+} $
and
$ M^{3+} $
in its oxide.Fraction of the metal which exists as
$ M^{3+} $
would be
JEE Main - 2013
JEE Main
Chemistry
The solid state
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