Question:

Which of the following vanadium pentahalides exists?

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Only fluoride is small and resistant enough to redox to form a stable pentahalide with V(V).
Updated On: Jul 3, 2026
  • VF5
  • VCl5
  • VBr5
  • VI5
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The Correct Option is A

Solution and Explanation

Step 1: V(V) is a strong oxidizer, easily reduced.
Step 2: Cl-, Br-, I- get oxidized by V5+, reducing it to V(IV).
Step 3: F- resists oxidation, so only VF5 is stable.
\[\boxed{VF_5}\]
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