Step 1: Recall the contact process.
In the contact process, sulphur dioxide:
\[
SO_2
\]
is first produced and then oxidized to:
\[
SO_3
\]
Step 2: Identify industrial sources of \(SO_2\).
Sulphur dioxide is commercially prepared by:
(i) Burning sulphur
\[
S+O_2\rightarrow SO_2
\]
and by roasting iron pyrites:
\[
4FeS_2+11O_2\rightarrow 2Fe_2O_3+8SO_2
\]
Thus, both:
\[
S \quad \text{and} \quad FeS_2
\]
are used as source materials.
Step 3: Check remaining options.
\[
FeS
\]
is not commonly used in contact process for \(SO_2\) manufacture.
\[
H_2S
\]
and
\[
Na_2S
\]
are also not industrial source materials used in the contact process.
Step 4: Final conclusion.
Hence, the correct answer is
\[
\boxed{S,\ FeS_2}
\]