Step 1: Concept
Alkaloids are classified based on their chemical structure, particularly the heterocyclic ring or carbon skeleton.
Step 2: Meaning
Phenethylamine alkaloids are characterized by a benzene ring attached to an ethylamine side chain.
Step 3: Analysis
Ephedra contains ephedrine and pseudoephedrine, which are structurally based on the phenethylamine skeleton. Atropine is a tropane alkaloid, and Coffee contains purine alkaloids.
Step 4: Conclusion
Thus, Ephedra is the primary source among the options for phenethylamine-type alkaloids.
Final Answer: (D)