Question:

Which of the following has highest second ionisation energy?

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Half-filled ($d^{5}$) and fully-filled ($d^{10}$) subshells have extra stability.
Updated On: Apr 8, 2026
  • Calcium
  • Chromium
  • Iron
  • Cobalt
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The Correct Option is B

Solution and Explanation

Step 1: Concept
Ionization energy depends on electronic configuration stability.
Step 2: Analysis

The configuration of $Cr$ is $[Ar] 3d^{5} 4s^{1}$. After losing one electron, $Cr^{+}$ achieves the stable $[Ar] 3d^{5}$ (half-filled) configuration.
Step 3: Conclusion

Removing a second electron from this stable half-filled d-orbital requires very high energy.
Final Answer: (B)
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