Step 1: Understand osmosis.
Osmosis is the movement of solvent molecules from a dilute solution to a concentrated solution through a semipermeable membrane.
The pressure required to stop this process is called osmotic pressure.
Step 2: Recall osmotic pressure equation.
According to van’t Hoff equation:
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where,
\[
\pi = \text{osmotic pressure}
\]
\[
C = \text{molar concentration}
\]
\[
R = \text{gas constant}
\]
\[
T = \text{absolute temperature}
\]
Step 3: Understand reverse osmosis.
In reverse osmosis, solvent is forced to move from concentrated solution to dilute solution by applying an external pressure greater than osmotic pressure.
Thus,
\[
P_{\text{ext}} \gt \pi
\]
Step 4: Substitute osmotic pressure value.
Since,
\[
\pi = CRT
\]
Therefore,
\[
P_{\text{ext}} \gt CRT
\]
Step 5: Final conclusion.
Hence, the correct condition for reverse osmosis is:
\[
\boxed{P_{\text{ext}} \gt CRT}
\]