Concept:
Alloys are mixtures of metals (or metals with non-metals) designed to enhance properties. Many common alloys contain copper as a major component.
Step 1: Check composition of each alloy.
• Brass → Copper + Zinc
• German Silver → Copper + Nickel + Zinc
• Bronze → Copper + Tin
• Solder → Lead + Tin (no copper)
Step 2: Identify alloy without copper.
Only solder does not contain copper.
Step 3: Final conclusion.
Thus, the correct answer is:
\[
Solder
\]