Step 1: Understanding the Concept:
One mole of a substance has a mass in grams equal to its molar mass.
So the mass of any amount is moles multiplied by molar mass.
Step 2: Find the Molar Mass of Water:
\(\text{H}_2\text{O}\): \(2\times 1 + 16 = 18\) g per mol.
Step 3: Calculate the Mass:
\[ m = n \times M = 0.25 \times 18 = 4.5 \text{ g} \]
Step 4: Check the Other Options:
\(0.25\) g is just the number of moles written as grams, a unit mix-up. \(18\) g is the mass of one full mole, four times too large. \(5.4\) g would come from using a wrong molar mass of 21.6 g per mol. So (A) is correct.
Final Answer:
0.25 mol of water has a mass of 4.5 g, which is option (A).
\[ \boxed{\text{(A) } 4.5\ \text{g}} \]