Step 1: Understanding the Concept:
Skim Milk Powder (SMP) is highly hygroscopic due to its high concentration of amorphous lactose, which readily absorbs moisture from the atmosphere if not packed in barrier packaging.
Step 2: Detailed Explanation:
When Skim Milk Powder absorbs moisture during improper storage:
• (A) Lactose Crystallization: Amorphous lactose absorbs water, transitions from a glassy state to a rubbery state, and crystallizes into \(\alpha\)-lactose monohydrate. (Correct)
• (D) Caking of SMP: As lactose crystallizes, it releases bound water and forms crystalline bridges between adjacent powder particles, causing them to clump together into hard lumps (caking). (Correct)
• (B) Maillard browning: The absorbed moisture increases water activity (\(a_w\)), which accelerates the Maillard reaction between the reducing sugar lactose and the lysine residues of milk proteins, leading to a brown discoloration and off-flavors. (Correct)
• (C) Coagulation of casein: Coagulation is a distinct enzymatic (rennet) or severe acid-induced precipitative process. Simple moisture absorption during powder storage does not cause casein coagulation. (Incorrect)
Therefore, the correct consequences of moisture uptake are (A), (B), and (D) only.
Step 3: Final Answer
The effects of moisture uptake in SMP are lactose crystallization, Maillard browning, and caking.