Step 1: Concept
If $\vec{A}+\vec{B}=\vec{C}$, then $C^2 = A^2 + B^2 + 2AB\cos\theta$.
Step 2: Meaning
Check if the magnitudes satisfy the Pythagorean theorem ($12, 5, 13$ is a known triplet).
Step 3: Analysis
$13^2 = 12^2 + 5^2 \implies 169 = 144 + 25 = 169$. This means $2AB\cos\theta = 0$.
Step 4: Conclusion
Since $\cos\theta = 0$, the angle between $\vec{A}$ and $\vec{B}$ is $90^{\circ}$.
Final Answer: (C)