Step 1: Identify the gas used in metal welding.
In metal welding, especially oxy-acetylene welding, the fuel gas used is acetylene:
\[
C_2H_2
\]
Acetylene burns in oxygen to produce a very high temperature flame.
Step 2: Write the combustion reaction.
The combustion of acetylene in oxygen is:
\[
2C_2H_2+5O_2\rightarrow4CO_2+2H_2O
\]
This reaction releases a large amount of heat and produces a flame temperature of about
\[
3000^\circ\text{C}
\]
which is sufficient for welding metals.
Step 3: Analyze the options.
(1) \(C_2H_4,\ O_2\): Ethylene is not commonly used for welding.
(2) \(C_4H_{10},\ O_2\): Butane is mainly used as fuel, not for welding.
(3) \(C_2H_2,\ N_2\): Nitrogen does not support combustion.
(4) \(C_2H_2,\ O_2\): Correct, this is the oxy-acetylene mixture used in welding.
Step 4: Final conclusion.
Hence, the gaseous mixture used for welding of metals is
\[
\boxed{C_2H_2,\ O_2}
\]